{"id":88,"date":"2021-01-26T17:11:50","date_gmt":"2021-01-26T22:11:50","guid":{"rendered":"https:\/\/web.uri.edu\/soft-matter-lab\/?page_id=88"},"modified":"2024-01-30T17:52:11","modified_gmt":"2024-01-30T22:52:11","slug":"research","status":"publish","type":"page","link":"https:\/\/web.uri.edu\/soft-matter-lab\/research\/","title":{"rendered":"Research"},"content":{"rendered":"\n<p>Our research group utilizes interdisciplinary approaches to produce novel soft materials that respond to their local environment or that possess novel functionality. We combine fundamental knowledge in the fields of chemical engineering, materials science, and physics to understand and manipulate the structure and dynamics of a wide range of soft matter building blocks, including polymers, colloids, and liquid droplets. Some of our current projects are described below.<\/p>\n\n\n\n<h1 class=\"wp-block-heading\">Current Projects<\/h1>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-layout-flow wp-block-column-is-layout-flow\">\n<h3 class=\"wp-block-heading\">Biomimetic Soft Matter<\/h3>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"732\" src=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-1024x732.jpg\" alt=\"\" class=\"wp-image-777\" srcset=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-1024x732.jpg 1024w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-300x214.jpg 300w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-768x549.jpg 768w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-364x260.jpg 364w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-500x357.jpg 500w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-1000x714.jpg 1000w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir-1280x915.jpg 1280w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Keane_Langmuir.jpg 1471w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><figcaption>Polymer molecular weight controls the structure of bridged emulsions (from <a rel=\"noreferrer noopener\" href=\"https:\/\/dx.doi.org\/10.1021\/acs.langmuir.3c00707\" target=\"_blank\">Keane, <em>et al.<\/em>, Langmuir, 2023<\/a>)<\/figcaption><\/figure>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p>We aim to design fully synthetic systems that replicate structures and functionality of biological systems. Current approaches include generating polymer-linked emulsions using novel triblock copolymers and mechanical capsules spontaneously nucleated through liquid-liquid phase separation.<\/p>\n\n\n\n<p>Block copolymer synthesis performed in collaboration with Dr. <a rel=\"noreferrer noopener\" href=\"https:\/\/vivo.brown.edu\/display\/bmcdona9\" target=\"_blank\">Benjamin McDonald<\/a> (Brown University, Department of Chemistry)<\/p>\n<\/div>\n<\/div>\n\n\n\n<h3 class=\"wp-block-heading\">Physics of the Yield Transition<\/h3>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"738\" src=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-1024x738.jpg\" alt=\"\" class=\"wp-image-797\" srcset=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-1024x738.jpg 1024w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-300x216.jpg 300w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-768x554.jpg 768w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-1536x1108.jpg 1536w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-2048x1477.jpg 2048w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-364x262.jpg 364w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-500x361.jpg 500w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-1000x721.jpg 1000w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-1280x923.jpg 1280w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP-2000x1442.jpg 2000w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/2023_Nikoumanesh_JCP.jpg 2316w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><figcaption>Serial creep divergence (SCD) identifies a bifurcation in the response of cellulose nanocrystal gels (from <a href=\"https:\/\/dx.doi.org\/10.1063\/5.0153644\" target=\"_blank\" rel=\"noreferrer noopener\">Nikoumanesh and RPS, JCP, 2023<\/a>)<\/figcaption><\/figure>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p>We investigate how soft materials transition from solid-like to liquid-like behaviors under stress to better understand bioengineering scaffolds and processing conditions of complex fluids. Our approach relies on the development of novel rheological protocols that isolate yielding in the presence of structural rearrangements and modeling the kinetics by which structural elements break and reform.<\/p>\n<\/div>\n<\/div>\n\n\n\n<h3 class=\"wp-block-heading\">Design of Complex Fluid Inks for Additive Manufacturing <\/h3>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-1024x497.jpg\" alt=\"\" class=\"wp-image-892\" width=\"319\" height=\"154\" srcset=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-1024x497.jpg 1024w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-300x146.jpg 300w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-768x373.jpg 768w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-364x177.jpg 364w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-500x243.jpg 500w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids-1000x486.jpg 1000w, https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PrintingFluids.jpg 1083w\" sizes=\"auto, (max-width: 319px) 100vw, 319px\" \/><figcaption>Enhanced printability through polymeric additives (<em>Unpublished<\/em>)<\/figcaption><\/figure>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p>Additive manufacturing (also known as 3D printing) can produce physical objects with a high degree of spatial resolution and on time scales orders of magnitude faster and cheaper than traditional manufacturing techniques. We identify the rheological properties of complex fluids necessary to facilitate direct-ink-writing (DIW) to improve formulation development and composition.<\/p>\n<\/div>\n<\/div>\n\n\n\n<h3 class=\"wp-block-heading\">Stability of Polymers in Natural Gas Environments<\/h3>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/PipelineProject-1024x356.jpg\" alt=\"\" class=\"wp-image-894\" width=\"316\" height=\"108\" \/><figcaption>Micromechanical testing of polymers for use in rehabilitating natural gas pipelines (<em>Unpublished<\/em>)<\/figcaption><\/figure>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p>Commercial and residential natural gas is delivered through an aging network of pipes, mostly cast iron, which are prohibitively expensive to replace. Instead, polymer liners can remediate the pipelines much more easily and cheaply. We quantify the stability of various polymers under exposure to natural gas environments to assess their performance over the next decades or century. <\/p>\n\n\n\n<p>Project in collaboration with Dr. <a rel=\"noreferrer noopener\" href=\"https:\/\/vivo.brown.edu\/display\/emathiow\" target=\"_blank\">Edith Mathiowitz<\/a> (Brown University) and Dr. <a rel=\"noreferrer noopener\" href=\"https:\/\/vivo.brown.edu\/display\/vsrivas1\" target=\"_blank\">Vikas Srivastava<\/a> (Brown University)<\/p>\n<\/div>\n<\/div>\n\n\n\n<h3 class=\"wp-block-heading\">Environmental Interfaces and Nanotechnology<\/h3>\n\n\n\n<div class=\"wp-block-columns is-layout-flex wp-container-core-columns-is-layout-9d6595d7 wp-block-columns-is-layout-flex\">\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:33.33%\">\n<figure class=\"wp-block-image size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/web.uri.edu\/soft-matter-lab\/wp-content\/uploads\/sites\/1895\/Environmental.jpg\" alt=\"\" class=\"wp-image-924\" width=\"319\" height=\"712\" \/><figcaption>Design of optically active nanoparticle suspensions for detecting environmental contaminants (<em>Unpublished<\/em>)<\/figcaption><\/figure>\n<\/div>\n\n\n\n<div class=\"wp-block-column is-vertically-aligned-center is-layout-flow wp-block-column-is-layout-flow\" style=\"flex-basis:66.66%\">\n<p>Our group is interested a number of questions regarding how the environment and microbes interact with soft matter interfaces. Specific thrusts include the development of polymer-grafted nanoparticle-based sensors to detect environmental contaminants, the characterization of biogenically produced inorganic nanoparticles, and the production of hierarchically structured anodes for benthic fuel cells.<\/p>\n\n\n\n<p>Projects primarily in collaboration with Dr. <a rel=\"noreferrer noopener\" href=\"https:\/\/web.uri.edu\/engineering\/meet\/vcraver\/\" target=\"_blank\">Vinka Craver<\/a> (URI, Department of Civil and Environmental Engineering) and Dr. <a href=\"https:\/\/web.uri.edu\/cheme\/meet\/irene-andreu\/\" data-type=\"URL\" data-id=\"https:\/\/web.uri.edu\/cheme\/meet\/irene-andreu\/\" target=\"_blank\" rel=\"noreferrer noopener\">Irene Andreu<\/a> (URI, Department of Chemical Engineering)<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>Our research group utilizes interdisciplinary approaches to produce novel soft materials that respond to their local environment or that possess novel functionality. We combine fundamental knowledge in the fields of chemical engineering, materials science, and physics to understand and manipulate the structure and dynamics of a wide range of soft matter building blocks, including polymers, [&hellip;]<\/p>\n","protected":false},"author":3845,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_acf_changed":false,"footnotes":"","_links_to":"","_links_to_target":""},"class_list":["post-88","page","type-page","status-publish","hentry"],"acf":[],"_links":{"self":[{"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/pages\/88","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/users\/3845"}],"replies":[{"embeddable":true,"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/comments?post=88"}],"version-history":[{"count":5,"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/pages\/88\/revisions"}],"predecessor-version":[{"id":987,"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/pages\/88\/revisions\/987"}],"wp:attachment":[{"href":"https:\/\/web.uri.edu\/soft-matter-lab\/wp-json\/wp\/v2\/media?parent=88"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}